Periodic table position of silicon and germanium (group classification) Silicon (Si) and germanium (Ge) belong to which column (group) of the periodic table?

Introduction / Context:
Semiconductors used in electronics—silicon and germanium—share chemical valence and occupy the same group in the periodic table. Their group position explains the four valence electrons, enabling tetrahedral bonding and the diamond/zinc-blende structures.

Given Data / Assumptions:

• Standard IUPAC numbering where Group 14 corresponds to the carbon family.
• Focus on main-group elements relevant to semiconductor physics.

Concept / Approach:
Group 14 (older notation: Group IV A) contains C, Si, Ge, Sn, Pb. Members have four valence electrons, forming four covalent bonds in typical semiconducting/elemental solids (Si, Ge), resulting in intrinsic semiconductivity with adjustable band structures upon alloying or doping.

Step-by-Step Solution:
Locate Si and Ge in the periodic table: both in Group 14.Relate group to valence (4) and to tetrahedral covalent bonding.Conclude: fourth column (Group 14) is correct.

Verification / Alternative check:
Introductory chemistry resources and semiconductor physics texts list Si and Ge as group-IV elements, the backbone of integrated-circuit technology and classic diodes/transistors.

Why Other Options Are Wrong:
Groups 2, 13, 15, 16 correspond to alkaline earths, triels, pnictogens, and chalcogens, none of which include both Si and Ge.

Common Pitfalls:

• Mixing old and new group numbering; “Group IV A” equals Group 14.

Final Answer:
Fourth column (Group 14)