Epoxy resins (epoxide polymers): select the statement that correctly describes a core chemical feature or processing trait of epoxy systems.
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AMade only by addition polymerisation reaction.
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BContain epoxy groups at the ends of the polymer chain prior to cure.
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CExist only as cross-linked polymers before use.
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DPrepared primarily via emulsion polymerisation methods.
Answer
Correct Answer: Contain epoxy groups at the ends of the polymer chain prior to cure.
Explanation
Introduction / Context:Epoxy resins are versatile thermosetting systems used in coatings, adhesives, laminates, and composites. Understanding their functional groups and curing chemistry ensures correct selection of hardeners and processing windows.
Given Data / Assumptions:
- Common epoxies are diglycidyl ethers (e.g., DGEBA) bearing terminal epoxide (oxirane) groups.
- Curing (with amines, anhydrides, etc.) converts these reactive ends into a crosslinked network.
- Manufacture involves step-growth reactions (not solely addition), and prepolymers are not crosslinked until cure.
Concept / Approach:The defining feature is the epoxide ring functionality at chain ends or along the backbone, enabling room-temperature or elevated-temperature curing. Prior to cure, epoxies are oligomeric liquids/solids with epoxy equivalents; after cure, they form a thermoset network. Emulsion polymerisation is not the primary production route.
Step-by-Step Solution:Identify signature chemistry: terminal epoxy groups.Eliminate claims of “only addition” and “already crosslinked.”Reject emulsion polymerisation as the typical route.
Verification / Alternative check:Technical datasheets specify epoxy equivalent weight (EEW), reflecting epoxide groups per mass prior to cure.
Why Other Options Are Wrong:(a) and (d) misstate mechanisms and methods; (c) describes the post-cure state, not the resin as supplied.
Common Pitfalls:Confusing epoxy “resin” (prepolymer) with the cured epoxy “thermoset.”
Final Answer:Contain epoxy groups at the ends of the polymer chain prior to cure.