In nylon-6 production from caprolactam, the typical conversion level achieved in the polymerisation step is approximately what percentage?
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A25
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B50
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C70
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D90
Answer
Correct Answer: 90
Explanation
Introduction / Context:Conversion in nylon-6 polymerisation impacts molecular weight, residual monomer content, and downstream devolatilisation requirements. High conversion is desired to minimise extractables and improve mechanical properties.
Given Data / Assumptions:
- Nylon-6 melt polymerisation is typically driven to high conversion before finishing/stripping.
- Residual caprolactam is later reduced via extraction or vacuum devolatilisation.
Concept / Approach:Industrial practice aims for high monomer-to-polymer conversion, often around 90% or above in the main reactor stage, followed by finishing steps to remove unreacted lactam and cyclic oligomers and to tune molecular weight by controlled solid-state or melt treatment.
Step-by-Step Solution:Select a high, realistic conversion target.90% aligns with common operations prior to finishing.
Verification / Alternative check:Process descriptions indicate high conversion with subsequent extraction to meet low residual monomer specs for fibres and films.
Why Other Options Are Wrong:25–70% are too low for efficient industrial practice and would leave excessive lactam.
Common Pitfalls:Assuming 100% conversion in practice; polymer processes usually approach but do not reach complete conversion before finishing.
Final Answer:90