Difficulty: Easy
Correct Answer: All of the above
Explanation:
Introduction / Context:
Many microbes secrete surface-active molecules (biosurfactants) such as rhamnolipids or proteins that alter gas–liquid interfacial properties. These changes can strongly influence foam formation, bubble size distributions, oxygen transfer, and antifoam requirements.
Given Data / Assumptions:
Concept / Approach:
Surfactants preferentially adsorb at interfaces, lowering surface tension. Lower surface tension and interfacial elasticity stabilize small bubbles and suppress coalescence, increasing gas holdup and often promoting foam stability. While this can improve interfacial area, it may reduce effective kLa if excessive foaming disrupts gas handling or causes flooding.
Step-by-Step Solution:
Verification / Alternative check:
Surface tension measurements (du Nouy ring, Wilhelmy plate) and bubble column tests show decreased σ and altered bubble size distribution in the presence of biosurfactants.
Why Other Options Are Wrong:
Common Pitfalls:
Assuming lower surface tension always increases kLa; excessive foaming can hinder mass transfer and operations.
Final Answer:
All of the above.
Discussion & Comments