Neutral refractory identification: among the following, which material is classified as a neutral refractory for many metallurgical environments?

Difficulty: Easy

Correct Answer: Graphite

Explanation:


Introduction / Context:
Refractories are often grouped as acidic, basic, or neutral, according to their chemical compatibility with slags and atmospheres. Selecting the correct class prevents premature corrosion and failure. Neutral refractories generally tolerate both acidic and basic environments better than strictly acidic or basic bricks.



Given Data / Assumptions:

  • Options include graphite, magnesite–chrome, silica, and magnesia.
  • Neutral means relatively stable to a range of slags, not strongly reactive with either acidic or basic melts.
  • Oxidation sensitivity is considered separately from acid/base classification.



Concept / Approach:
Silica is acidic; magnesia and magnesite–chrome are basic. Graphite, while susceptible to oxidation at high temperature in oxidizing atmospheres, is chemically neutral to many slags and molten metals and is widely used in neutral or carbon-containing linings, tundish boards, crucibles, and as a component in alumina–carbon/magnesia–carbon bricks.



Step-by-Step Solution:
Classify each option: silica → acidic; magnesia and magnesite–chrome → basic; graphite → neutral.Account for practical caveat: graphite must be protected from oxidation, e.g., by inert/reducing atmosphere or resin/antioxidant additions.Therefore, the neutral refractory among the options is graphite.



Verification / Alternative check:
Materials handbooks list graphite and chromite as neutral classes, contrasting them with high-silica (acidic) and magnesia (basic) bricks.



Why Other Options Are Wrong:
Magnesite chrome and magnesia: basic class.Silica: acidic class.



Common Pitfalls:
Conflating oxidation behaviour with acid/base classification; assuming “neutral” means universally inert under all conditions.



Final Answer:
Graphite

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