Highest melting pure oxide (> 3000 °C): which oxide among the following has the highest melting point and is used in extreme-temperature refractory applications?

Difficulty: Easy

Correct Answer: Thoria (ThO2)

Explanation:


Introduction / Context:
Melting point is a key indicator for selecting refractories for ultra-high temperature service. Pure oxides such as thoria, zirconia, alumina, and beryllia differ substantially in melting temperatures, thermal conductivities, and chemical stabilities.


Given Data / Assumptions:

  • We focus on pure oxides and their intrinsic melting points.
  • “Highest” implies comparing representative literature values.


Concept / Approach:
Thoria (ThO2) exhibits one of the highest melting points among common refractory oxides, generally quoted above 3000 °C (around 3300 °C). Zirconia and beryllia melt in the mid-to-upper 2000 °C range, and alumina near ~2050 °C. Hence ThO2 tops this list for extreme temperature stability.


Step-by-Step Solution:

Recall typical melting points: ThO2 > 3000 °C; ZrO2 ≈ 2700 °C; BeO ≈ 2570 °C; Al2O3 ≈ 2050 °C.Identify the maximum: ThO2.Choose Thoria (ThO2).


Verification / Alternative check:
High-temperature materials references consistently list thoria at the top among these oxides; it has been used historically in crucibles and special electrodes where temperature extremes are encountered.


Why Other Options Are Wrong:

Alumina/beryllia/zirconia: high-melting but below thoria’s value.Hafnia is very high-melting (~2750–2800 °C) yet still below thoria in most tables.


Common Pitfalls:
Confusing service temperature with melting point; ignoring destabilization by impurities or atmosphere.


Final Answer:
Thoria (ThO2)

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