Identify the non-oxide refractory: which of the following is not a single-oxide refractory material?

Difficulty: Easy

Correct Answer: Silicon carbide (SiC)

Explanation:


Introduction / Context:
Refractories are classified by chemistry into oxide, non-oxide, and carbonaceous groups. Single-oxide refractories are based on one dominant oxide (e.g., Al2O3, MgO, ZrO2). Non-oxide ceramics such as carbides, nitrides, and borides offer excellent high-temperature strength and thermal shock resistance but behave differently in oxidizing atmospheres.


Given Data / Assumptions:

  • The question targets the chemical type, not brand names.
  • We must choose the material that is not a single oxide.


Concept / Approach:
Zirconia (ZrO2) and magnesia (MgO) are classic single-oxide refractories. Silicon carbide (SiC) is a non-oxide ceramic compound and thus not a single oxide. Therefore, SiC is the correct choice.


Step-by-Step Solution:

List compositions: ZrO2 → oxide; MgO → oxide; SiC → carbide (non-oxide).Apply category definition: “single-oxide” excludes carbides.Select Silicon carbide (SiC).


Verification / Alternative check:
Handbooks group SiC with non-oxide refractories used for kiln furniture and crucibles, particularly where thermal shock is critical.


Why Other Options Are Wrong:

Zirconia and magnesia are single-oxide refractories.Chromia (if considered) is also a single-oxide refractory (Cr2O3).“None of these” is incorrect because one option (SiC) is clearly non-oxide.


Common Pitfalls:
Confusing “oxide content” with “single-oxide class”; overlooking that SiC oxidizes to SiO2 at high temperature in oxidizing atmospheres.


Final Answer:
Silicon carbide (SiC)

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