Refractive index of petrofuel — what does it indicate? The refractive index (n) of a petroleum fuel, defined as the ratio of light speed in air to that in the fuel, generally correlates with its ______.
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AMolecular weight
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BAromatics content
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CBoth a & b
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DNeither a nor b
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EOnly sulfur content
Answer
Correct Answer: Both a & b
Explanation
Introduction / Context:Simple optical properties such as refractive index provide rapid, non-destructive indication of hydrocarbon composition. Refineries use n and derived quantities (e.g., refractivity intercept) for quality checks.
Given Data / Assumptions:
- Comparisons among similar boiling range fuels (to avoid volatility confounding).
Concept / Approach:Refractive index increases with increasing average molecular weight and with higher aromatic content (due to higher polarizability). Thus, n qualitatively indicates both. It is not a sulfur-specific metric. Consequently, the best answer is “Both a & b.”
Step-by-Step Solution:
Recall polarizability trends: aromatics > naphthenes > paraffins.Heavier molecules also raise n.Select combined correlation.Verification / Alternative check:Empirical correlations (e.g., refractivity intercept) relate n and density to composition and average molecular weight.
Why Other Options Are Wrong:
- “Only” statements omit the dual dependence.
- “Neither” contradicts established correlations.
Common Pitfalls:Comparing across very different boiling ranges; always compare within similar distillate cuts.
Final Answer:Both a & b