Petroleum product properties: Identify the single incorrect statement about specific gravity and energy content of hydrocarbon families.

Difficulty: Medium

Correct Answer: Aromatics have lower specific gravity than corresponding paraffins.

Explanation:


Introduction:
The question tests understanding of how specific gravity correlates with hydrogen-to-carbon ratio and how energy content compares across hydrocarbon families (paraffins vs aromatics) on mass and volume bases.


Given Data / Assumptions:

  • Compare paraffins (alkanes) and aromatics.
  • Relate specific gravity to C/H ratio and energy content.
  • Assume typical petroleum-range hydrocarbons.


Concept / Approach:
As specific gravity increases, the average hydrogen content per carbon generally decreases (more condensed structures), increasing the C/H ratio. Energy content comparisons depend on whether we consider per unit mass or per unit volume.


Step-by-Step Solution:

Step 1: Option A: Higher specific gravity → higher C/H ratio (less hydrogen per carbon). This is broadly correct.Step 2: Option B: Claims aromatics have lower specific gravity than paraffins. In reality, aromatics usually have higher specific gravity than corresponding paraffins, so B is incorrect.Step 3: Option C: On a mass basis, paraffins tend to have higher heating value per kilogram than aromatics; low specific gravity correlates with higher mass-based heating value—so C is correct.Step 4: Option D: On a volume basis, higher specific gravity often translates to higher energy per litre; aromatics thus provide higher volumetric energy—so D is correct.Step 5: Option E restates the mass-basis comparison in favour of paraffins—correct.


Verification / Alternative check:
Fuel property tables show paraffinic streams have higher MJ/kg, whereas denser aromatic streams exhibit higher MJ/L.


Why Other Options Are Wrong:

  • Only Option B is wrong; A, C, D, and E align with standard trends.


Common Pitfalls:
Mixing up mass-basis and volume-basis energy content; assuming one family dominates on both metrics.


Final Answer:
Aromatics have lower specific gravity than corresponding paraffins.

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