Polarization of a rare gas in an electric field A rare (noble) gas with number density N (atoms per m^3) is subjected to a uniform electric field E. In the linear regime, the macroscopic electric dipole moment per unit volume (polarization P) is proportional to which quantities?
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AProportional to N and to E (P ∝ N E)
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BIndependent of N, proportional only to E
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CIndependent of E, proportional only to N
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DProportional to N but inversely proportional to E
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EProportional to E^2 only
Answer
Correct Answer: Proportional to N and to E (P ∝ N E)
Explanation
Introduction / Context:In dielectric media, polarization P gives the dipole moment per unit volume. For dilute gases such as noble gases, induced dipoles arise via electronic polarizability, and the Clausius–Mossotti/Lorentz–Lorenz relations connect microscopic polarizability to macroscopic P.
Given Data / Assumptions:
- Dilute gas, non-interacting atoms with electronic polarizability αe.
- Linear response (small fields).
- Number density N (atoms/m^3) and applied field E.
Concept / Approach:
Each atom acquires an induced dipole p_induced = αe E (in SI, αe may be written with ε0 depending on convention). The polarization is P = N * p_induced, so P ∝ N * E. Hence, doubling the density or the field doubles P in the linear regime.
Step-by-Step Solution:
Write single-atom response: p = αe E.Sum over N atoms in unit volume: P = N αe E.Conclude P ∝ N and P ∝ E.Verification / Alternative check:
Macroscopic dielectric constant εr relates to microscopic αe via Lorentz–Lorenz relation; for small αe N, the linear dependence is clear.
Why Other Options Are Wrong:
Independence from N or E contradicts linear polarization theory; E^2 dependence appears in nonlinear optics, not in this small-signal regime.
Common Pitfalls:
Confusing microscopic polarizability with relative permittivity, or assuming strong-field nonlinear effects at ordinary field strengths.
Final Answer:
Proportional to N and to E (P ∝ N E)