Addition polymerization – common plastics produced by chain-growth mechanism The method of addition (chain-growth) polymerization is used to obtain which of the following plastics?

Difficulty: Easy

Correct Answer: All of these

Explanation:


Introduction / Context:
Plastics used in building services, packaging, and consumer goods are formed by different polymerization routes. Distinguishing addition (chain-growth) from condensation (step-growth) polymerization helps predict properties, processing, and recycling behavior. This question asks which common plastics are produced via the addition mechanism.


Given Data / Assumptions:

  • Addition polymerization involves unsaturated monomers forming chains without losing small molecules.
  • Monomers include ethylene, propylene, vinyl chloride, and styrene.
  • We pick all that fit the chain-growth route.


Concept / Approach:

Polyethylene, polypropylene, polyvinyl chloride, and polystyrene are all produced by addition polymerization. In each case, double-bond-containing monomers (or vinyl monomers) undergo initiation, propagation, and termination to form long chains. No small by-product (like water or HCl from the reaction itself) is eliminated during chain growth; PVC contains chlorine in the monomer structure but is still polymerized additively.


Step-by-Step Solution:

1) Identify monomer types: ethylene, propylene, vinyl chloride, styrene → all vinyl-type monomers.2) Recognize mechanism: radical, ionic, or coordination (Ziegler–Natta/Metallocene) addition polymerization.3) Conclude all listed plastics arise from addition polymerization.


Verification / Alternative check:

Polymer science references classify PE, PP, PVC, and PS as chain-growth polymers, in contrast to condensation polymers like polyesters, polyamides, and phenol-formaldehyde resins.


Why Other Options Are Wrong:

Each individual option names a plastic correctly produced by addition polymerization; hence only the combined choice covers them all.


Common Pitfalls:

Assuming PVC is condensation because of chlorine presence; confusing chain-growth with step-growth mechanisms; overlooking catalyst roles (e.g., Ziegler–Natta) that still operate via addition pathways.


Final Answer:

All of these

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