Industrial applications of C4 dienes: Identify the principal industrial use of 1,3-butadiene in large-scale chemical manufacturing.

Chemical Engineering Polymer Technology Difficulty: Easy
Choose an option
  • A
    as an anti-skimming agent in paint
  • B
    as a plasticizer for unsaturated polyester
  • C
    in the manufacture of synthetic rubber
  • D
    none of these

Answer

Correct Answer: in the manufacture of synthetic rubber

Explanation

Introduction / Context:1,3-Butadiene is a key petrochemical building block. Understanding its dominant application highlights connections between monomer markets and end-use sectors like automotive tires, footwear, hoses, and vibration-damping components.

Given Data / Assumptions:

  • We consider global bulk usage patterns rather than specialty niche uses.
  • Common copolymerization partners include styrene and acrylonitrile.
  • Evaluation concerns the largest consumption pathway.

Concept / Approach:Butadiene’s conjugated diene structure makes it ideal for producing elastomers. The major products are SBR (styrene-butadiene rubber), PBR (polybutadiene rubber), and NBR (acrylonitrile-butadiene rubber). These elastomers dominate tire treads, sidewalls, and impact-modified plastics (e.g., ABS uses butadiene in the rubbery phase).

Step-by-Step Solution:

List candidate uses: additives in paints/plasticizers vs. elastomer manufacture.Compare market volumes: elastomers represent the overwhelming share of butadiene demand.Select the dominant use: manufacture of synthetic rubber.

Verification / Alternative check:Industry reports consistently show SBR and PBR as principal outlets for butadiene, driven by tire production volumes worldwide.

Why Other Options Are Wrong:

  • Anti-skimming in paint: Not a primary or large-volume use for butadiene monomer.
  • Plasticizer for unsaturated polyester: Plasticizers are different compounds; butadiene is a monomer for elastomers, not a typical plasticizer.
  • None of these: Incorrect since the elastomer route is correct.

Common Pitfalls:Confusing butadiene’s role in ABS (impact modifier phase) with plasticization; it is chemically part of a copolymer, not a free plasticizer.

Final Answer:in the manufacture of synthetic rubber

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