Formaldehyde-based resins: which polymer family belongs to the class of formaldehyde resins used for hard, cross-linked thermosets?
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AMelamine–formaldehyde resins
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BPolytetrafluoroethylene (Teflon)
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CPolyethylene terephthalate (Dacron)
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DNone of these
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EPolycarbonate (bisphenol-A type)
Answer
Correct Answer: Melamine–formaldehyde resins
Explanation
Introduction:Formaldehyde resins cover urea–formaldehyde, phenol–formaldehyde, and melamine–formaldehyde systems. They are classic thermosets used in laminates, molded parts, and surface finishes due to hardness, heat resistance, and dimensional stability.
Given Data / Assumptions:
- We seek a resin whose chemistry explicitly reacts with formaldehyde to form a cross-linked network.
- Other options list common thermoplastics unrelated to formaldehyde chemistry.
Concept / Approach:Melamine–formaldehyde resins result from condensation of melamine with formaldehyde and cure into hard, glossy thermosets. Teflon, PET, and polycarbonate are thermoplastics prepared by entirely different monomers and mechanisms.
Step-by-Step Solution:Identify formaldehyde resin family member: melamine–formaldehyde → correct.Eliminate non-formaldehyde thermoplastics (PTFE, PET, PC).Select option (a).
Verification / Alternative check:Materials references list MF resins as decorative laminates (e.g., table tops), dishes, and coatings with high hardness.
Why Other Options Are Wrong:
- PTFE: fluoropolymer from tetrafluoroethylene; no formaldehyde.
- PET (Dacron): polyester from ethylene glycol + terephthalic acid.
- Polycarbonate: from bisphenol-A + phosgene or transesterification; not a formaldehyde resin.
Common Pitfalls:Confusing “resin” as a generic term with formaldehyde-based thermoset chemistry; formaldehyde resins are a specific class.
Final Answer:Melamine–formaldehyde resins