Applied polymer science: which low-molecular-weight (below about 10^4), soft and waxy polymer is commonly used as a chewing-gum base ingredient?
-
ACellulose acetate
-
BPolyvinyl acetate (PVAc)
-
CPolysulfide rubber (Thiokol)
-
DPolyvinyl chloride (PVC)
-
ELow-density polyethylene (LDPE) homopolymer
Answer
Correct Answer: Polyvinyl acetate (PVAc)
Explanation
Introduction:Chewing-gum formulations rely on a food-grade, soft, and slightly tacky polymer base. The question checks recognition of PVAc as a classic gum base polymer due to its mouthfeel, film-forming ability, and safety profile in regulated applications.
Given Data / Assumptions:
- Target polymer is soft/waxy and low in molecular weight (sub-10^4 region).
- Food-contact compliance and taste neutrality are required.
- Processing involves plasticizers and flavors added to the base.
Concept / Approach:Polyvinyl acetate provides suitable viscoelastic properties, acceptable adhesion, and compatibility with plasticizers. Alternatives like PVC or Thiokol are not food-grade choices; cellulose acetate can be film-forming but is not the standard gum base polymer in this context.
Step-by-Step Solution:Identify candidate with food use track record: PVAc is widely cited as a gum base.Screen out engineering/industrial polymers (PVC, Thiokol) unsuited for ingestion.Confirm low-MW PVAc grades exhibit the soft, waxy characteristics described.Select PVAc as correct.
Verification / Alternative check:Food additive references list PVAc (and certain elastomers) as common chewing-gum base components, blended with plasticizers like triacetin and resins.
Why Other Options Are Wrong:
- Cellulose acetate: used for films/coatings; not the principal gum base polymer.
- Thiokol: sulfur-based polysulfide rubber with strong odor, not food-grade gum base.
- PVC and LDPE: unsuitable for chewing gum bases under typical food regulations and performance needs.
Common Pitfalls:Assuming any soft thermoplastic can serve as gum base; regulatory and sensory requirements are stringent.
Final Answer:Polyvinyl acetate (PVAc)