Organic chemistry (isomerism): What type of isomerism exists between CH₃CHCl₂ and CH₂Cl–CH₂Cl (two dichloroethane isomers)? Compare the position of substituents on the same carbon skeleton. Choose the correct option.

IIT JEE Chemistry Difficulty: Easy
Choose an option
  • A
    Chain isomerism
  • B
    Functional group isomerism
  • C
    Positional isomerism
  • D
    Metamerism

Answer

Correct Answer: Positional isomerism

Explanation

Given structures

  • CH₃–CHCl₂ (1,1-dichloroethane)
  • CH₂Cl–CH₂Cl (1,2-dichloroethane)

Concept/ApproachSame carbon skeleton and same functional groups (halo), but different positions of substituents ⇒ positional isomerism.

Final AnswerPositional isomerism

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