Difficulty: Easy
Correct Answer: m v r = n h / (2π)
Explanation:
Introduction / Context:
Bohr’s model introduces the postulate that the orbital angular momentum of an electron in a hydrogen-like atom is quantized in integer multiples of ħ = h / (2π). Although superseded by full quantum mechanics, this condition still yields correct energy levels for hydrogen and is foundational in the historical development of atomic theory.
Given Data / Assumptions:
Concept / Approach:
Bohr’s postulate: L = m v r = n ħ = n h / (2π), where n = 1, 2, 3, …. Only those orbits with angular momentum equal to an integer multiple of ħ are allowed. This leads to quantized radii r_n and energy levels E_n that match observed spectral lines via the Rydberg formula.
Step-by-Step Solution:
Verification / Alternative check:
Using m v r = n h / (2π) and Coulomb force balance m v^2 / r = k e^2 / r^2 gives r_n ∝ n^2 and E_n ∝ −1/n^2, in agreement with hydrogen spectra.
Why Other Options Are Wrong:
(b) misses the 2π factor; (c) uses wrong mechanical quantity; (d) inverts the variables and is dimensionally inconsistent.
Common Pitfalls:
Confusing angular momentum quantization with de Broglie standing wave condition; they are equivalent but require careful use of 2π.
Final Answer:
m v r = n h / (2π)
Discussion & Comments