For a monatomic ideal gas, what is the ratio of specific heats (Cp/Cv), commonly denoted as gamma?

Difficulty: Easy

Correct Answer: 1.66

Explanation:


Introduction / Context:
The ratio of specific heats γ = Cp/Cv influences speed of sound, isentropic relations, and compressor/expander performance. For monatomic gases, γ takes a characteristic value based on degrees of freedom from kinetic theory.


Given Data / Assumptions:

  • Monatomic ideal gas (e.g., He, Ne, Ar).
  • Equipartition of energy applies.


Concept / Approach:
For a monatomic gas, translational degrees of freedom = 3. Then Cv = (3/2)R (molar basis) and Cp = Cv + R = (5/2)R. Therefore, γ = Cp/Cv = (5/2)R / (3/2)R = 5/3 ≈ 1.66.


Step-by-Step Solution:

Cv = 3/2 * R.Cp = Cv + R = 5/2 * R.γ = Cp/Cv = (5/2 R)/(3/2 R) = 5/3 ≈ 1.66.


Verification / Alternative check:
Experimental values for noble gases at room temperature (e.g., argon) cluster near 1.66, validating the kinetic theory model.


Why Other Options Are Wrong:

  • 1.44 and 1.99: Not consistent with monatomic degrees of freedom.
  • 1: Would imply Cp = Cv, which is not true for gases.


Common Pitfalls:
Confusing monatomic with diatomic gases (which have γ ≈ 1.4 at room temperature) and using the wrong γ in isentropic equations.


Final Answer:
1.66

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