Comparing acidity using pH: A solution with pH = 5 is less acidic than a solution with pH = 2 by what factor? (Assume 25°C and aqueous solutions.)
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A3
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B100
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C1000
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Dnone of these
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E30
Answer
Correct Answer: 1000
Explanation
Introduction / Context:The pH scale is logarithmic, not linear. Every one-unit change corresponds to a tenfold change in hydrogen ion concentration. Converting qualitative statements like “more acidic” into quantitative factors is a routine task in water chemistry, bioprocessing, and environmental engineering.
Given Data / Assumptions:
- Definition: pH = −log10[H+].
- Two solutions: pH1 = 5 and pH2 = 2.
- Temperature and activity corrections are neglected for this comparison (typical for textbook problems).
Concept / Approach:The acidity comparison factor is the ratio of hydrogen ion concentrations. Because pH is a base-10 logarithm, a difference of ΔpH corresponds to a factor of 10^ΔpH in [H+]. Lower pH means higher [H+] (more acidic). We compute the factor by evaluating 10^(pH_high − pH_low).
Step-by-Step Solution:
ΔpH = 5 − 2 = 3.Factor difference in [H+] = 10^3 = 1000.Therefore, the pH 5 solution is 1000 times less acidic (i.e., has 1000 times lower [H+]) than the pH 2 solution.Verification / Alternative check:Compute [H+] explicitly: at pH 2, [H+] = 10^−2 M; at pH 5, [H+] = 10^−5 M. Ratio = (10^−2)/(10^−5) = 10^3 = 1000.
Why Other Options Are Wrong:
- 3: Mistakenly treats the scale as linear.
- 100: Only accounts for a 2-unit change, not the full 3 units.
- None of these / 30: Not supported by the logarithmic definition.
Common Pitfalls:Forgetting the logarithmic nature of pH; mixing up which solution is more acidic; confusing “times less acidic” with differences in pH units.
Final Answer:1000