Phenolic vs other thermosets: formaldehyde condenses with which substrate to produce a non-phenolic resin?
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AResorcinol
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BPhenol
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CPara-cresol
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DMelamine
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ECatechol
Answer
Correct Answer: Melamine
Explanation
Introduction / Context:Condensation of formaldehyde with various nucleophilic substrates yields different thermoset families. Phenolic resins result from phenol-formaldehyde reactions, while melamine-formaldehyde resins constitute a separate class with distinct performance.
Given Data / Assumptions:
- Phenolic substrates include phenol, resorcinol, and p-substituted phenols like p-cresol.
- Melamine is a triazine amine, not a phenolic compound.
- Formaldehyde acts as a crosslinker via methylol formation.
Concept / Approach:Phenolic resins require phenolic hydroxyl groups. Amino resins (e.g., melamine–formaldehyde) form by condensation at amino groups, producing methylene and methylene-ether linkages typical of MF resins, known for hardness and heat resistance.
Step-by-Step Solution:List phenolic candidates: phenol, resorcinol, para-cresol.Identify melamine as non-phenolic (amino) substrate.Therefore, melamine with formaldehyde does not produce a phenolic resin.
Verification / Alternative check:Commercial tabletop laminates and dinnerware often use melamine–formaldehyde, not phenolics, highlighting the different resin family.
Why Other Options Are Wrong:Phenol/resorcinol/p-cresol all yield phenolic-type networks with formaldehyde.
Common Pitfalls:Assuming all formaldehyde condensations are “phenolic”; overlooking amino resins as a major thermoset class.
Final Answer:Melamine