Donor dopants (pentavalent): Which of the following is a commonly used pentavalent dopant for creating n-type semiconductor material?
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Aarsenic
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Bboron
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Cgallium
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Dneon
Answer
Correct Answer: arsenic
Explanation
Introduction / Context:Doping tailors semiconductor conductivity by adding controlled impurities. Pentavalent dopants (Group V) donate extra electrons and produce n-type material. Recognizing common dopants is essential for understanding device fabrication and the electrical behavior of junctions.
Given Data / Assumptions:
- Target: n-type doping (donor).
- Periodic table groups govern valence electron count and bonding possibilities in silicon lattices.
- Common, practical dopants are considered.
Concept / Approach:Pentavalent atoms such as phosphorus (P), arsenic (As), and antimony (Sb) have five valence electrons. When substituted into a silicon lattice (valence 4), one electron remains weakly bound and can be easily promoted to conduction, yielding an electron-rich (n-type) semiconductor. Trivalent dopants (Group III) like boron (B) and gallium (Ga) create p-type material by accepting electrons (creating holes).
Step-by-Step Solution:
Identify the valence of each option: As (Group V) → pentavalent.B and Ga (Group III) → trivalent, used for p-type doping.Neon is a noble gas (Group 18), chemically inert; not used as a dopant.Verification / Alternative check:Standard semiconductor texts and process notes list P, As, Sb as donor species. As is common in diffusion and ion implantation steps for forming shallow, well-controlled junctions.
Why Other Options Are Wrong:
- Boron and gallium: p-type (acceptors), not pentavalent donors.
- Neon: Inert gas; does not form the necessary covalent bonds in silicon.
Common Pitfalls:Confusing donors and acceptors due to periodic table position. Remember: Group V → n-type; Group III → p-type.
Final Answer:arsenic