Nature of covalent bonding in semiconductors Electron-pair bonding in a crystal lattice occurs when atoms do which of the following?

Difficulty: Easy

Correct Answer: share electrons

Explanation:


Introduction / Context:
Covalent bonding underpins the structure of semiconductor crystals. Understanding how atoms bond helps explain band formation, carrier generation, and the operation of diodes and transistors.


Given Data / Assumptions:

  • Group IV semiconductor lattice (e.g., silicon).
  • Stable, periodic crystal with sp³ hybridization.


Concept / Approach:
In covalent bonds, neighboring atoms share pairs of electrons to complete their outer shells. In silicon, each atom shares one electron with each of four neighbors, forming four electron-pair bonds. At finite temperature, breaking some bonds generates mobile carriers (electrons and holes).


Step-by-Step Solution:
Recognize covalent bond definition: shared electron pairs between atoms.Apply to semiconductors: four shared pairs per atom in the tetrahedral lattice.Infer: electron-pair bonding equals sharing electrons.Therefore, the correct description is “share electrons.”


Verification / Alternative check:
Band theory derivations begin with covalent bonding and result in valence and conduction bands separated by a bandgap appropriate to shared-electron systems.


Why Other Options Are Wrong:
Lack electrons/holes: describes defect states, not the bonding mechanism.Share holes: holes are the absence of electrons; the bond itself is electron sharing.


Common Pitfalls:
Thinking of holes as physical particles in bonds; bonds involve electrons, while holes are mobile vacancies influencing conduction.


Final Answer:
share electrons

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