Fuel composition: For the following fuels, which has the highest carbon-to-hydrogen ratio by weight—gasoline, kerosene, light gas oil, or heavy fuel oil?

Difficulty: Easy

Correct Answer: Heavy fuel oil

Explanation:

Introduction / Context:Carbon/hydrogen (C/H) ratio by weight is a useful indicator of fuel heaviness and combustion characteristics. As hydrocarbon chains become heavier and more aromatic, the C/H ratio typically increases, affecting energy content, smoke tendency, and emissions.Given Data / Assumptions:

  • We compare typical petroleum products: gasoline, kerosene, light gas oil (LGO), and heavy fuel oil (HFO).
  • We assume conventional refinery specifications without unusual additives.
  • C/H ratio is by weight.

Concept / Approach:Lighter distillates (gasoline, kerosene) have higher hydrogen-to-carbon relative content and more paraffinic composition. As products get heavier (LGO → HFO), average molecular weight increases, aromaticity often rises, and the hydrogen fraction drops, raising the C/H ratio.Step-by-Step Solution:

Step 1: Order the products by typical boiling range: gasoline < kerosene < LGO < HFO.Step 2: Recognize that the heaviest product generally exhibits the highest C/H ratio.Step 3: Select heavy fuel oil as having the maximum C/H by weight.

Verification / Alternative check:Elemental analyses of refinery streams consistently show heavier residual fuels with lower hydrogen content (by wt%), hence higher C/H ratios than lighter distillates.Why Other Options Are Wrong:

  • Light gas oil: Heavier than kerosene/gasoline but lighter than HFO; C/H lower than HFO.
  • Kerosene: Mid-distillate with higher hydrogen fraction than LGO/HFO.
  • Gasoline: Lightest among the four; typically the lowest C/H ratio.

Common Pitfalls:Confusing H/C atomic ratio with C/H weight ratio; regardless of expression, heavier residual fuels have relatively less hydrogen.Final Answer:Heavy fuel oil

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