Biogas composition – identify the FALSE statement: Which statement below about the composition of biogas is NOT true in standard anaerobic digestion systems?
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AIt consists almost exclusively of methane and carbon dioxide as major components.
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BIt also contains traces of hydrogen sulfide, nitrogen, hydrogen, and carbon monoxide.
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CIt also contains notable traces of oxygen and chlorine gas under normal operation.
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DBoth (a) and (b) are true statements about typical biogas.
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ETrace constituents vary with feedstock and process conditions.
Answer
Correct Answer: It also contains notable traces of oxygen and chlorine gas under normal operation.
Explanation
Introduction / Context: Biogas from anaerobic digesters powers combined heat and power units and is upgraded to biomethane. Knowing its typical composition is essential for safety, corrosion control, and process monitoring.
Given Data / Assumptions:
- Primary components: methane (usually 50–70%) and carbon dioxide (30–50%).
- Common trace gases: H2S (corrosive), NH3 (occasionally), N2, H2, and CO in small amounts.
- Anaerobic systems exclude oxygen; chlorine gas is not a normal product.
Concept / Approach: In anoxic digesters, oxygen is absent because it is consumed rapidly and the process is sealed; thus O2 is near zero. Chlorine gas is not produced by anaerobic microbial pathways. Therefore any statement claiming typical O2 and Cl2 presence is false. Statements about methane/CO2 dominance and trace H2S/N2/H2/CO are accurate.
Step-by-Step Solution: List expected major and trace components of biogas. Check each statement against process chemistry and microbiology. Identify the incorrect claim: presence of oxygen and chlorine gas. Select the false statement as the answer.
Verification / Alternative check: Gas analyzer readings from digesters report CH4 and CO2 with ppm–percent H2S; O2 alarms usually indicate leaks or air ingress, not normal operation.
Why Other Options Are Wrong: Major CH4/CO2 and the listed traces accurately describe biogas; process variability (option e) also holds true.
Common Pitfalls: Assuming oxygen persists inside sealed digesters or confusing chlorine used in sanitation with gaseous Cl2 in product gas.
Final Answer: It also contains notable traces of oxygen and chlorine gas under normal operation..