Industrial salts – starting material for alum manufacture Which substance is used as the principal starting raw material for manufacturing alum (e.g., potash alum)?
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Aalumina
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Bgypsum
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Cbauxite
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Dammonium bicarbonate
Answer
Correct Answer: bauxite
Explanation
Introduction / Context:Alum (commonly potassium aluminium sulfate dodecahydrate) is used in water treatment, paper sizing, and dyeing. The route to alum industrially depends on an aluminium-bearing ore that can be dissolved and converted efficiently.
Given Data / Assumptions:
- Commercial alum production targets Al-bearing feedstocks.
- Bauxite is the most abundant economical source of aluminium compounds.
- Options include pure chemicals and non-aluminium minerals.
Concept / Approach:Bauxite (a hydrated aluminium oxide ore) is acid-leached to extract aluminium, which is then reacted (commonly with potassium sulfate) to crystallize alum. While alumina is a refined product from bauxite, industry typically references bauxite as the starting raw material for alum manufacture rather than purchasing high-purity alumina for this purpose.
Step-by-Step Solution:
Identify practical, economical Al source → bauxite.Recognize that gypsum and ammonium bicarbonate do not supply aluminium.Select bauxite as the correct starting raw material.Verification / Alternative check:Standard inorganic chemical technology texts describe alum preparation from bauxite via acid digestion followed by crystallization with appropriate alkali metal sulfate.
Why Other Options Are Wrong:
- Alumina: A refined material; not the usual ‘‘starting’’ ore feed in bulk alum production context.
- Gypsum: Calcium sulfate; no aluminium.
- Ammonium bicarbonate: Provides ammonium/carbonate; no aluminium.
Common Pitfalls:Assuming the refined intermediate (alumina) is the designated raw material; in commodity manufacture, the ore (bauxite) is the common starting point.
Final Answer:bauxite