Lime materials — properties of quicklime (CaO) Which statements correctly describe quicklime used in construction materials and chemical processes?

Civil Engineering Building Materials Difficulty: Easy
Choose an option
  • A
    It is obtained by calcination of pure limestone (CaCO3).
  • B
    It has strong affinity for moisture (hygroscopic).
  • C
    It is amorphous in structure.
  • D
    All of the above
  • E
    It is pre-hydrated and non-reactive

Answer

Correct Answer: All of the above

Explanation

Introduction / Context:Quicklime (calcium oxide) is a key material for soil stabilization, mortar production, and environmental applications. Knowing its origin and behavior is crucial for safe handling and effective use at site.

Given Data / Assumptions:

  • Limestone is primarily CaCO3.
  • Calcination occurs in kilns at elevated temperatures.
  • Quicklime reacts exothermically with water to form slaked lime (Ca(OH)2).

Concept / Approach:Calcination drives CO2 off limestone, producing CaO. The product is highly reactive with water and atmospheric moisture, which is why storage must be dry and airtight. Quicklime is generally non-crystalline (amorphous) as produced industrially, contributing to its reactivity.

Step-by-Step Solution:Calcination: CaCO3 → CaO + CO2 (endothermic decomposition).Hygroscopic behavior: CaO readily hydrates → Ca(OH)2 with substantial heat release.Material structure: commonly amorphous/finely crystalline, aiding rapid reaction.Therefore, all three statements are correct.

Verification / Alternative check:Industrial datasheets list loss on ignition, free CaO content, and storage precautions due to moisture affinity.

Why Other Options Are Wrong:The extra option claiming pre-hydrated and non-reactive contradicts the very definition of quicklime; pre-hydrated material is slaked lime, not quicklime.

Common Pitfalls:Exposing quicklime to ambient humidity leading to unsafe heat release; mistaking hydrated lime for quicklime in mix designs; ignoring purity effects on performance.

Final Answer:All of the above

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