Difficulty: Easy
Correct Answer: increasing the internal energy of gas and also for doing some external work
Explanation:
Introduction / Context:
Specific heats at constant pressure (cp) and constant volume (cv) differ because, at constant pressure, a portion of the heat input must push back the surroundings as the gas expands. This explains why cp > cv for ideal gases.
Given Data / Assumptions:
Concept / Approach:
First law for a quasi-static process: δQ = dU + δW. At constant pressure, δW = p dV. For an ideal gas, dU = m * cv * dT, and δQ = m * cp * dT, with cp = cv + R (per unit mass basis), showing that part of the heat goes into internal energy rise and part into boundary work.
Step-by-Step Solution:
Write δQ = dU + p dV.Use ideal-gas relation at constant p: p dV = m R dT.Relate internal energy change: dU = m cv dT.Thus δQ = m (cv dT + R dT) = m cp dT, where cp = cv + R.Interpretation: heat input raises internal energy and performs external work simultaneously.
Verification / Alternative check:
Calorimetry experiments consistently measure cp > cv, directly confirming that additional heat beyond dU is required to provide boundary work at constant pressure.
Why Other Options Are Wrong:
Common Pitfalls:
Confusing heat (a path function) with internal energy (a state property). The split cp = cv + R captures the dual role of the heat input at constant pressure.
Final Answer:
increasing the internal energy of gas and also for doing some external work
Discussion & Comments