Gas cooled at constant pressure (qualitative behavior): When a gas is cooled at constant pressure, what happens to its temperature and volume?

Difficulty: Easy

Correct Answer: both temperature and volume decreases

Explanation:


Introduction / Context:
Many real processes approximate constant-pressure behavior, such as heating or cooling in ducts and atmospheric processes. Understanding the qualitative change in volume with temperature at constant pressure is a direct application of the ideal gas law and is vital for interpreting P–V–T diagrams and process narratives.


Given Data / Assumptions:

  • Ideal gas behavior for qualitative trends.
  • Pressure p held constant externally.
  • No phase change within the temperature range considered.


Concept / Approach:
The ideal gas equation pV = mRT shows V ∝ T at fixed p and mass. Therefore, reducing T (cooling) directly reduces V at constant p. Temperature obviously decreases by definition of cooling. Thus, both the temperature and the volume decrease during constant-pressure cooling.


Step-by-Step Solution:

Hold p constant: pV = mRT ⇒ V = mR*T/p.Decrease T: T ↓ implies V ↓ proportionally.Hence, both T and V fall when cooling at constant p.


Verification / Alternative check:
On a T–V diagram at constant p, the process traces a straight line through the origin (for ideal gas), confirming direct proportionality between V and T.


Why Other Options Are Wrong:

  • Temperature increases while cooling: Contradiction in terms.
  • Volume increases under cooling at constant p: Opposite of ideal gas relation.
  • Both increase: Again contradicts cooling definition and gas law.


Common Pitfalls:
Confusing constant-pressure with constant-volume or constant-temperature processes; forgetting to hold mass constant when applying pV = mRT.


Final Answer:
both temperature and volume decreases

More Questions from Thermodynamics

Discussion & Comments

No comments yet. Be the first to comment!
Join Discussion