Ore beneficiation methods: Froth flotation is most suitable for the separation and upgrading of which type of ores?
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AIron ores (primarily hematite) without prior preparation
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BSulphide ores (e.g., galena, sphalerite, chalcopyrite)
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CQuartzite (massive silica rock)
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DNone of these
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EBauxite (gibbsite) directly without desilication
Answer
Correct Answer: Sulphide ores (e.g., galena, sphalerite, chalcopyrite)
Explanation
Introduction / Context:Froth flotation is a selective separation technique based on differences in surface hydrophobicity. It revolutionized mineral processing by enabling efficient concentration of low-grade ores, especially sulfides, at relatively fine particle sizes.
Given Data / Assumptions:
- Appropriate reagents (collectors, frothers, modifiers) are available.
- Ores are ground to liberate valuable minerals from gangue.
- Pulp chemistry (pH, ionic strength) can be adjusted to achieve selectivity.
Concept / Approach:Sulfide minerals bond well with xanthates and related collectors, rendering them hydrophobic. Air bubbles attach to hydrophobic particles, which rise to form a froth concentrate. Gangue (e.g., silicates) remains hydrophilic and sinks as tailings. This makes sulfide ores ideal candidates for flotation.
Step-by-Step Solution:Identify ore type with strong collector response: sulfides.Apply grinding and reagent scheme to selectively float the valuable sulfide minerals.Collect froth concentrate; depress unwanted minerals as needed (e.g., Zn vs Pb selectivity).
Verification / Alternative check:Historical and modern concentrators for Pb–Zn–Cu rely primarily on froth flotation; iron ores more commonly use magnetic or gravity separation (though reverse flotation is used in some hematite systems after desliming and reagentization).
Why Other Options Are Wrong:
- Iron ores/quartzite: not typically floated as primary step without significant conditioning; magnetic/gravity often dominate.
- Bauxite: processed mainly by digestion (Bayer process), not by simple flotation at mine scale.
- None of these: incorrect because sulfide ores are the classic flotation feeds.
Common Pitfalls:Overlooking liberation: insufficient grinding yields poor flotation performance regardless of reagents.
Final Answer:Sulphide ores (e.g., galena, sphalerite, chalcopyrite)