Factors affecting scaling of furnace stock The rate at which oxide scale forms on heated stock is governed by which combination of variables?
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Atemperature
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Btime
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Cnature of atmosphere
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Dall (a), (b) and (c)
Answer
Correct Answer: all (a), (b) and (c)
Explanation
Introduction / Context: Scaling is oxidation of metal surfaces at elevated temperatures. In reheating and heat treatment, minimizing scale is essential to preserve surface quality and reduce material losses.
Given Data / Assumptions:
- Oxidizing environments promote scale formation.
- Kinetics are temperature and time dependent.
Concept / Approach: Oxidation rates typically increase strongly with temperature (Arrhenius-type behavior). Longer exposure time increases total scale thickness. The furnace atmosphere (oxidizing vs reducing, moisture content, CO2/CO ratio) also changes the oxidation rate and type of scale formed. Thus, temperature, time, and atmosphere all matter.
Step-by-Step Solution:
Relate temperature to reaction rate: higher T ⇒ faster oxidation.Relate time to accumulated growth: longer time ⇒ thicker scale.Relate atmosphere to mechanism: oxidizing species concentration controls driving force.Conclude that all listed variables govern scaling.Verification / Alternative check: Practical data show reduced scaling with shorter cycles and controlled (less oxidizing) atmospheres at a given temperature.
Why Other Options Are Wrong:
Each single factor alone cannot explain observed differences when others change.Common Pitfalls: Overheating periods “just to be safe,” which disproportionately increases scale due to strong temperature sensitivity.
Final Answer: all (a), (b) and (c)