Gas sweetening absorbents — ethanolamine service Ethanolamine solutions (e.g., MEA) are commonly employed to remove which contaminant(s) from process gas or air streams?

Difficulty: Easy

Correct Answer: H2S

Explanation:


Introduction / Context:
Amine treating (gas sweetening) is a standard process for purifying natural gas, refinery gases, and synthesis gas. Ethanolamine (MEA) is a primary amine absorbent used to capture acid gases through reversible chemical reactions.



Given Data / Assumptions:

  • The absorbent is ethanolamine (MEA) in aqueous solution.
  • Common acid gas contaminants include H2S and CO2.
  • We select among HF, SO2, H2S, or a combination.


Concept / Approach:
MEA reacts readily with hydrogen sulfide (H2S) and carbon dioxide (CO2), forming protonated amine salts or carbamates that are later regenerated by heating and pressure reduction. Industrially, MEA is not the standard reagent for flue-gas SO2 scrubbing (limestone, lime, or ammonia solutions are typical). HF handling requires specialized sorbents or aqueous neutralization, not MEA.



Step-by-Step Solution:

Map amine chemistry: MEA + H2S ⇌ MEAH⁺ + HS⁻; MEA + CO2 ⇌ MEA–carbamate + H⁺.Exclude HF: incompatible and hazardous for amine circuits.Exclude SO2: FGD typically uses alkaline slurries; amine loops target H2S/CO2.Select H2S as the correct contaminant removed by ethanolamine.


Verification / Alternative check:
Standard process design texts list MEA units as H2S/CO2 removal (sweetening) steps ahead of sulfur recovery units (Claus) in refineries and gas plants.



Why Other Options Are Wrong:

HF: Not treated by MEA absorption; specialized systems are required.SO2 / both (b) & (c): SO2 is typically not removed by MEA in industrial practice; combining with H2S is misleading.


Common Pitfalls:
Assuming all acid gases behave similarly in all absorbents; process selection depends on kinetics, corrosion, and regeneration practicality.



Final Answer:
H2S

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