Asphyxiant in air — toxicology threshold Which pollutant causes death by asphyxiation if its concentration in atmospheric air exceeds the maximum allowable level (greater than about 50 ppm)?

Difficulty: Easy

Correct Answer: Carbon monoxide

Explanation:


Introduction / Context:
Asphyxiants interfere with oxygen delivery to tissues. Recognizing the most dangerous low-level asphyxiant in urban air is essential for safety, environmental monitoring, and public health.



Given Data / Assumptions:

  • The threshold mentioned (~50 ppm) is an order-of-magnitude cue for acute concern.
  • Candidates include carcinogens, oxidants, and a well-known hemoglobin-binding gas.


Concept / Approach:
Carbon monoxide (CO) binds hemoglobin with much higher affinity than oxygen, forming carboxyhemoglobin and reducing blood’s oxygen-carrying capacity. Even tens of ppm for prolonged exposure can cause symptoms; higher concentrations lead to loss of consciousness and death. The others listed are harmful but do not produce classic hemoglobin-related asphyxiation at such low ppm levels.



Step-by-Step Solution:

Identify the asphyxiation mechanism: hemoglobin binding → impaired oxygen transport.Match to pollutant: CO is the classic chemical asphyxiant at relatively low ppm.Eliminate alternatives: benzopyrene (carcinogen), PAN (photochemical irritant), SO2 (respiratory irritant).Select carbon monoxide as the correct answer.


Verification / Alternative check:
Toxicology references list exposure guidelines and health effects for CO, showing rapid onset of hypoxia symptoms as concentrations rise above tens to hundreds of ppm.



Why Other Options Are Wrong:

Benzopyrene: Polycyclic aromatic carcinogen; not an acute asphyxiant.Peroxyacyl nitrate: Eye/respiratory irritant in photochemical smog; not primarily asphyxiating.Sulphur dioxide: Potent irritant and bronchoconstrictor; asphyxiation is not its principal mode at 50 ppm.


Common Pitfalls:
Assuming any toxic gas at 50 ppm causes asphyxiation; the unique hemoglobin affinity of CO makes it particularly dangerous.



Final Answer:
Carbon monoxide

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