In solid-state magnetism, materials that lack permanent magnetic dipoles (and develop only weak, negative magnetization in an applied field) are classified as which type?

Electronics and Communication Engineering Materials and Components Difficulty: Easy
Choose an option
  • A
    Paramagnetic
  • B
    Diamagnetic
  • C
    Ferromagnetic
  • D
    Ferrimagnetic
  • E
    Antiferromagnetic

Answer

Correct Answer: Diamagnetic

Explanation

Introduction / Context:Magnetic behavior of materials arises from electron spins and orbital motions. Whether a solid exhibits a net permanent moment depends on the presence of unpaired spins and cooperative ordering. This question checks the basic classification when no permanent dipoles exist in the absence of a field.

Given Data / Assumptions:

  • No permanent magnetic dipoles; all atomic or molecular moments cancel out in zero field.
  • Consider response in a weak, applied magnetic field.
  • Temperature is not driving long-range magnetic order (no ferromagnetic or ferrimagnetic states).

Concept / Approach:Diamagnetic materials have all electrons paired; they exhibit an induced magnetic moment opposite to the external field due to Lenz-like response of orbital motion, giving a small negative susceptibility. Paramagnets have unpaired electrons that align weakly with the field (positive susceptibility) but no permanent magnetization without a field. Ferromagnets and ferrimagnets show spontaneous ordering and domain behavior leading to permanent dipoles.

Step-by-Step Solution:

Identify the absence of permanent dipoles → rules out ferro-, ferri-, and antiferromagnets in their ordered states.Paramagnets still possess permanent atomic moments (unpaired spins) even if disordered → not suitable.Materials with paired electrons only exhibit diamagnetism with negative susceptibility.

Verification / Alternative check:

Examples: bismuth, copper, and superconductors (perfect diamagnetism in the Meissner state) demonstrate diamagnetic behavior.

Why Other Options Are Wrong:

Paramagnetic: contains permanent dipoles from unpaired spins.Ferromagnetic/Ferrimagnetic: possess domain magnetization and remanence.Antiferromagnetic (not listed in stem but as an option): still has ordered sublattice spins, although net moment may cancel; not “no permanent dipoles.”

Common Pitfalls:

Equating “no net moment” with “no dipoles”; antiferromagnets have opposing sublattice dipoles, not the absence of dipoles.

Final Answer:

Diamagnetic
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