In petroleum product finishing and purification, clay treatment (adsorptive contacting with activated clay/earth) is primarily used to remove which objectionable constituents, particularly from cracked gasoline and similar streams?

Difficulty: Easy

Correct Answer: Colour and dissolved gases from cracked gasoline

Explanation:


Introduction:
Clay treatment is a classic adsorption-based polishing step used in petroleum refining to improve the appearance and stability of products, most notably cracked gasoline and certain kerosene fractions. Understanding what clay treatment actually removes helps avoid confusing it with entirely different unit operations such as electrical desalting or solvent dewaxing.


Given Data / Assumptions:

  • The term “clay treatment” refers to contacting product with activated clay/bleaching earth or fuller’s earth, followed by filtration.
  • Typical applications include cracked gasoline and kerosene-range streams where colour bodies, trace gum precursors, and dissolved gases/odorous species are present.
  • It is not a primary salt/water removal or wax-removal process.


Concept / Approach:
Activated clays have a high surface area and polar sites that adsorb coloured compounds (poly-aromatics, resinous species), certain sulfur-oxygen species, and other trace contaminants. In cracked gasoline, clay contacting can lighten colour and reduce objectionable odor or dissolved gas content that might otherwise impair stability or customer perception.


Step-by-Step Solution:
1) Identify the adsorptive nature of clay treatment and its common targets: colour bodies and trace reactive species.2) Recognize its typical service: polishing of cracked gasoline/kerosene to improve colour and stability.3) Exclude operations that require entirely different physics/chemistry (e.g., desalting or dewaxing).


Verification / Alternative check:
Refinery practice distinguishes clay treating (adsorption) from electric desalting (water/salt removal), caustic washing (acidic species neutralization), and solvent dewaxing (crystallization/filtration). Vendor literature and standard manuals list “colour improvement and odor reduction” as the main benefits for gasoline-range products.


Why Other Options Are Wrong:
Salt removal from crude: Done by electrical desalters with dilution water.Wax removal: Achieved by solvent dewaxing (e.g., MEK–toluene) or chilling/filtration, not clays.None of these / coalescence: Do not describe adsorption polishing.


Common Pitfalls:
Confusing clay treatment with bleaching of edible oils or with acid/caustic treating; while analogous in concept, petroleum clay contacting has distinct targets and is not a desalting or dewaxing shortcut.


Final Answer:
Colour and dissolved gases from cracked gasoline

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