Ideal-gas Charles law application: At constant pressure, to double the volume of a given mass of an ideal gas initially at 27°C, to what temperature (°C) must it be raised?
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A270
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B327
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C300
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D540
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E87
Answer
Correct Answer: 327
Explanation
Introduction / Context:Charles law for ideal gases states that, at constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature. This principle underlies many heating and expansion calculations for gases in process equipment and lab settings.
Given Data / Assumptions:
- Ideal-gas behavior.
- Initial temperature T1 = 27°C.
- Final volume V2 = 2V1 at the same pressure.
- Absolute temperature in kelvin is required for proportionality.
Concept / Approach:
At constant pressure: V ∝ T(K). Therefore, V2/V1 = T2/T1. Convert Celsius to kelvin by adding 273.15. Doubling volume requires doubling the absolute temperature. After finding the final kelvin temperature, convert back to °C for the answer format.
Step-by-Step Solution:
Convert initial temperature: T1 = 27 + 273.15 ≈ 300 K.Use proportionality: V2/V1 = 2 ⇒ T2 = 2T1 ≈ 600 K.Convert T2 to °C: 600 − 273.15 ≈ 326.85°C ≈ 327°C.Verification / Alternative check:
A quick ratio check: if T doubles in kelvin, V must double at constant pressure. The numeric conversion confirms 327°C.
Why Other Options Are Wrong:
270 or 300°C do not reflect doubling to 600 K. 540°C corresponds to 813 K (more than double). 87°C equals 360 K, not double.
Common Pitfalls:
Forgetting to convert to kelvin; attempting to double the Celsius value instead of the absolute temperature value.
Final Answer:
327