Gas laws – precise statement of Boyle’s law Choose the correct form of Boyle’s law for a fixed mass of an ideal gas at constant temperature (isothermal conditions).

Difficulty: Easy

Correct Answer: P * V = constant, at constant temperature and fixed mass of gas

Explanation:


Introduction / Context:
Boyle’s law is one of the foundational gas laws used to describe the behavior of ideal gases. It underlies isothermal compression/expansion calculations in compressors, syringes, and many laboratory operations.


Given Data / Assumptions:

  • Ideal gas behavior assumed.
  • Temperature held constant (isothermal process).
  • Amount of gas (number of moles) held constant.


Concept / Approach:
For an isothermal change of a fixed mass of an ideal gas, pressure is inversely proportional to volume. Mathematically, P ∝ 1/V, which integrates to P * V = constant. Either expression is a correct statement of Boyle’s law; the most explicit engineering form used for calculations is P1V1 = P2V2 when comparing two states at the same temperature and moles.


Step-by-Step Solution:

Recognize isothermal, fixed-mass scenario.Use Boyle’s relation: P ∝ 1/V.Write the constant-product form: P * V = constant.Select the explicit constant-product statement as the best answer.


Verification / Alternative check:
From the ideal gas law PV = nRT, holding n and T constant gives PV = constant, confirming Boyle’s law directly.


Why Other Options Are Wrong:

  • P ∝ V: Opposite of Boyle’s law.
  • P/T = constant: That is Gay-Lussac’s relation for fixed V, not Boyle’s law.
  • P ∝ 1/V is conceptually correct, but the most complete engineering statement is the constant-product form selected.


Common Pitfalls:
Forgetting the “fixed mass and constant temperature” conditions; mixing Boyle’s law with Charles’ or Gay-Lussac’s laws.


Final Answer:
P * V = constant, at constant temperature and fixed mass of gas

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