Cast irons — improving toughness by annealing with hematite When cast iron is heated to red heat in contact with powdered red hematite to increase toughness, it is converted into:
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Agrey cast iron
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Bwhite cast iron
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Cmottled cast iron
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Dtoughed cast iron
Answer
Correct Answer: toughed cast iron
Explanation
Introduction / Context:Malleabilisation (toughening) of cast iron is a heat-treatment process that transforms an otherwise brittle structure into a tougher product suitable for parts like fittings and brackets. The question refers to annealing with oxidising media (red hematite).
Given Data / Assumptions:
- Heating to red heat for prolonged time in the presence of hematite (an oxidising environment).
- Starting material is typically white cast iron (cementite present).
- Objective is to increase ductility and toughness.
Concept / Approach:Under oxidising/annealing conditions, combined carbon (cementite) decomposes, producing temper carbon nodules within a ferritic matrix. The resulting product is often termed malleable or toughened cast iron (here listed as “toughed cast iron”).
Step-by-Step Solution:
Heat white cast iron in hematite-packed pots to red heat for long durations.Allow cementite to decompose → precipitation of temper carbon.Achieve ferrite-rich matrix with temper carbon → improved toughness and machinability.Verification / Alternative check:Microstructural examination shows reduction in carbides and presence of temper carbon; mechanical testing confirms increased elongation and impact resistance.
Why Other Options Are Wrong:
- Grey cast iron (A): contains graphite flakes formed on solidification, not via this post-solidification malleabilising route.
- White cast iron (B): starting point; it is hard and brittle, not the toughened end product.
- Mottled cast iron (C): intermediate mixture of white and grey structures, not the toughened, malleable product.
Common Pitfalls:Confusing grey iron (flake graphite) with malleable iron (temper carbon nodules). The oxidising pack anneal specifically aims at malleabilisation, not graphitisation during casting.
Final Answer:
toughed cast iron