Difficulty: Easy
Correct Answer: Triple superphosphate (monocalcium phosphate rich)
Explanation:
Introduction / Context:
Superphosphates are described by their dominant phosphate species. The formula CaH4(PO4)2 is another way of writing Ca(H2PO4)2, the monocalcium phosphate that constitutes the active, water-soluble component of triple superphosphate (TSP). Recognizing this mapping is useful when cross-referencing fertilizer labels and chemical formulations.
Given Data / Assumptions:
Concept / Approach:
Because TSP is largely monocalcium phosphate with minimal gypsum, the neat formula Ca(H2PO4)2 is commonly associated with TSP in textbook representations. SSP, while containing the same monocalcium species, also contains 2 CaSO4 equivalents (gypsum), so it is not represented simply by Ca(H2PO4)2. Tricalcium phosphate corresponds to rock phosphate; metaphosphoric acid is a condensed phosphate, not a calcium salt.
Step-by-Step Solution:
Verification / Alternative check:
Manufacturing routes and product specifications list TSP as primarily monocalcium phosphate, while SSP is Ca(H2PO4)2 + CaSO4.
Why Other Options Are Wrong:
Common Pitfalls:
Assuming SSP and TSP are chemically identical; they differ in concentration and associated salts, even though both contain monocalcium phosphate.
Final Answer:
Triple superphosphate (monocalcium phosphate rich).
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