For an ideal gas, the average translational kinetic energy per molecule depends only on which parameter?

Difficulty: Easy

Correct Answer: absolute temperature

Explanation:


Introduction / Context:
Kinetic theory links macroscopic temperature to microscopic molecular motion. In the ideal gas model, translational kinetic energy is solely temperature dependent.



Given Data / Assumptions:

  • Ideal gas behavior.
  • Equipartition theorem applies.
  • Focus on translational degrees of freedom.



Concept / Approach:
The average translational kinetic energy per molecule is (3/2) k_B T, where k_B is Boltzmann’s constant and T is absolute temperature. It is independent of the gas species or molecular size in the ideal approximation.



Step-by-Step Solution:
Write relation: E_trans,avg = (3/2) k_B T.Note species independence: no molecular parameter other than T appears.Hence, the correct determinant is absolute temperature.



Verification / Alternative check:
Root-mean-square speed v_rms ∝ sqrt(T/M) varies with molar mass, but energy ~ (1/2) m v^2 averages to (3/2) k_B T, removing species dependence.



Why Other Options Are Wrong:
Nature or size of the gas affects collision dynamics and real-gas deviations, not the ideal-gas energy–temperature relation.



Common Pitfalls:
Confusing speed dependence on molar mass with energy dependence on temperature.



Final Answer:
absolute temperature


Discussion & Comments

No comments yet. Be the first to comment!
Join Discussion