Assertion–Reason: magnetic susceptibility of copper and diamagnetism Assertion (A): The magnetic susceptibility of copper is approximately −0.5 × 10^−5. Reason (R): Copper is a diamagnetic material.
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ABoth A and R are true and R is correct explanation of A
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BBoth A and R are true but R is not correct explanation of A
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CA is true but R is false
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DA is false but R is true
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ENeither A nor R is true
Answer
Correct Answer: Both A and R are true and R is correct explanation of A
Explanation
Introduction / Context:Magnetic susceptibility χ indicates how a material responds to an applied magnetic field. Diamagnets develop a small magnetization opposite to the applied field, yielding negative susceptibility values. Copper is a canonical example used in basic magnetism courses.
Given Data / Assumptions:
- SI convention for volume magnetic susceptibility (dimensionless).
- Weak-field, room-temperature conditions.
- Isotropic bulk copper sample.
Concept / Approach:Diamagnetism arises from induced orbital currents that oppose the change in magnetic flux (Lenz-like behavior at the electronic level). For diamagnetic materials, χ < 0, typically with small magnitude (10^−6 to 10^−5). Copper, although a good electrical conductor, exhibits net diamagnetism after accounting for the contributions of conduction and core electrons, with χ around −10^−5.
Step-by-Step Solution:Assess Assertion: χ(Cu) ≈ −0.5 × 10^−5 → a small negative number → consistent with diamagnetism.Assess Reason: “Copper is diamagnetic” correctly describes its sign of χ.Causality: Being diamagnetic explains why the susceptibility is negative and small → R explains A.
Verification / Alternative check:Handbooks list copper’s susceptibility close to −10^−5. Sign and magnitude agree with the assertion and the rationale of diamagnetism.
Why Other Options Are Wrong:(b) claims no explanatory link, but diamagnetism directly accounts for negative χ. (c) and (d) contradict established data. (e) is incorrect because both statements are true.
Common Pitfalls:
- Confusing diamagnetism (negative χ) with paramagnetism (positive χ).
- Mixing volume and molar susceptibility units; the sign remains negative.
Final Answer:Both A and R are true and R is correct explanation of A