Refrigerant safety comparison: Which of the following refrigerants is both highly toxic and flammable under typical service conditions?

Mechanical Engineering Heat Transfer, Refrigeration and Air Conditioning Difficulty: Easy
Choose an option
  • A
    Ammonia (R-717)
  • B
    Carbon dioxide (R-744)
  • C
    Sulphur dioxide (R-764)
  • D
    R-12 (dichlorodifluoromethane)
  • E
    R-134a (1,1,1,2-Tetrafluoroethane)

Answer

Correct Answer: Ammonia (R-717)

Explanation

Introduction / Context:Refrigerant selection weighs thermodynamic performance against safety and environmental criteria. Toxicity and flammability classifications (e.g., ISO/ASHRAE) guide application choices.

Given Data / Assumptions:

  • Standard industrial interpretations of toxicity and flammability.
  • Normal HVAC&R service pressures and temperatures.
  • Generalized safety classes (e.g., ammonia A3/B2L type considerations).

Concept / Approach:Ammonia (R-717) is efficient but toxic and mildly flammable; it requires stringent safety measures (ventilation, detectors, restricted occupancy). CO2 (R-744) is non-toxic and non-flammable but operates at high pressure. SO2 is toxic but not commonly classified as flammable in HVAC usage. R-12 and R-134a are non-flammable and of low acute toxicity (environmental concerns aside).

Step-by-Step Solution:

Assess toxicity: Ammonia and SO2 are toxic; CO2 and common fluorocarbons have low acute toxicity.Assess flammability: Ammonia is flammable in certain concentration ranges; SO2 is not typically treated as flammable in refrigeration contexts.Therefore, the only option that is both toxic and flammable is ammonia.Hence, choose Ammonia (R-717).

Verification / Alternative check:Safety standards place ammonia systems in machinery rooms with ventilation and leak detection; CO2 systems focus more on pressure management and asphyxiation risks, not flammability.

Why Other Options Are Wrong:CO2 is non-flammable; SO2 is toxic but not flammable; R-12 and R-134a are non-flammable and lower acute toxicity (though they have environmental impacts).

Common Pitfalls:Confusing toxicity with asphyxiation risk; CO2 can displace oxygen but is not flammable.

Final Answer:Ammonia (R-717)

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