Definition check: in refractory engineering, “spalling” refers to which failure phenomenon?
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AGeneral softening at temperature
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BFracture or flaking due to uneven expansion at high temperature (thermal shock)
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CResistance to compressive loads
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DResistance to chemical attack by gases and molten fluxes
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EUniform plastic deformation under load
Answer
Correct Answer: Fracture or flaking due to uneven expansion at high temperature (thermal shock)
Explanation
Introduction / Context:Spalling is a major cause of premature refractory failure, especially in units that cycle frequently or face steep temperature gradients. Correctly defining spalling helps diagnose root causes and choose preventive measures.
Given Data / Assumptions:
- Thermal cycling or local hot spots are present.
- Material exhibits cracking, flaking, or shelling.
- Definition sought, not a test method.
Concept / Approach:Spalling is the cracking and detachment of surface layers caused by thermal stresses arising from non-uniform expansion or sudden temperature changes. It is distinct from softening, chemical corrosion, or creep. Materials with low thermal expansion, controlled porosity, and microcrack networks resist spalling better.
Step-by-Step Solution:Relate thermal gradients to internal stresses.Connect stresses to crack initiation at flaws/pores.Define the observed outcome: flaking/fracture of the hot face.
Verification / Alternative check:Thermal shock tests (quench cycling) quantify spalling resistance and correlate with service outcomes.
Why Other Options Are Wrong:Softening is a separate rheological response.Load resistance and chemical resistance are different property domains.
Common Pitfalls:Equating any crack with chemical attack; spalling is a mechanical/thermal phenomenon.
Final Answer:Fracture or flaking due to uneven expansion at high temperature (thermal shock)