Universal gas constant R: Choose the correct value in kcal per kg-mol per °C (practical engineering units).
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A2.79
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B1.987
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C3.99
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Dnone of these
Answer
Correct Answer: 1.987
Explanation
Introduction / Context:The universal gas constant R appears in equations of state (e.g., PV = nRT) and energy relations. Engineers often use convenient unit systems; one common choice is kcal per kg-mol per K (or °C for incremental differences).
Given Data / Assumptions:
- Reference values: R = 8.314 kJ/mol·K = 1.987 kcal/mol·K.
- In many chemical engineering texts, “kg-mol” is used synonymously with “kmol” and retains the same numerical constant when paired consistently with other units.
Concept / Approach:Unit conversions: 1 kcal = 4.184 kJ. Therefore 8.314 kJ/mol·K ÷ 4.184 ≈ 1.987 kcal/mol·K. In engineering usage this is frequently written per kg-mol·K with the same numerical value when moles are the basis entity in the chosen unit system.
Step-by-Step Solution:
Start: R = 8.314 kJ/mol·K.Convert: 8.314 / 4.184 ≈ 1.987 kcal/mol·K.Adopt engineering format: 1.987 kcal/(kg-mol·°C) (incremental °C ≡ K).Verification / Alternative check:Cross-check with English units: R ≈ 1.987 Btu/lb-mol·°R, consistent numerically, confirming the conversion pattern.
Why Other Options Are Wrong:
- 2.79 and 3.99 are not equal to R in these units.
- “None of these” is incorrect because 1.987 is correct and widely used.
Common Pitfalls:Mixing per mol and per kmol without adjusting other units; always keep unit systems internally consistent.
Final Answer:1.987