Crystal structures of iron — phase identification: Which type of space lattice is exhibited by alpha-iron (ferrite) at room temperature?
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Aface-centred cubic (FCC) space lattice
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Bbody-centred cubic (BCC) space lattice
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Cclose-packed hexagonal (HCP) space lattice
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Dnone of these
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Etetragonal martensitic lattice
Answer
Correct Answer: body-centred cubic (BCC) space lattice
Explanation
Introduction / Context:Iron exhibits allotropic transformations, changing its crystal structure with temperature. Recognizing the structure of alpha-iron at ambient conditions is foundational for understanding steel heat treatment, diffusion, and mechanical behavior.
Given Data / Assumptions:
- Alpha-iron (ferrite) is stable below approximately 912°C.
- Question targets the room-temperature lattice type.
- Common structures: BCC, FCC, HCP.
Concept / Approach:At room temperature, pure iron exists as ferrite with a BCC lattice. Upon heating above about 912°C up to 1394°C, iron becomes austenite with FCC structure, and above that transforms again before melting. Martensite is a supersaturated, distorted tetragonal phase formed by rapid quenching in steels rather than a stable form of pure iron.
Step-by-Step Solution:Identify the temperature range for ferrite: below ~912°C.Recall that alpha-iron (ferrite) → BCC lattice.Eliminate FCC (austenite) and HCP (not a phase of pure iron at ambient).Select BCC as the correct lattice for alpha-iron.
Verification / Alternative check:Phase diagrams and metallurgy texts corroborate BCC ferrite at room temperature with low carbon solubility.
Why Other Options Are Wrong:FCC corresponds to gamma-iron (austenite); HCP is not a stable crystal structure for pure iron under normal conditions; “none of these” and “tetragonal martensitic” do not describe alpha-iron.
Common Pitfalls:Confusing ferrite and austenite stability ranges or equating martensite (a non-equilibrium phase) with base iron structures.
Final Answer:body-centred cubic (BCC) space lattice