Bohr–de Broglie relation: The number of standing de Broglie waves fitting an electron’s circular orbit equals the principal quantum number <em>n</em>. If the maximum magnetic quantum number is +3 (so l = 3), determine the number of waves for the lowest allowed orbit with that l. Choose the correct option.

IIT JEE Chemistry Difficulty: Medium
Choose an option
  • A
    3
  • B
    4
  • C
    5
  • D
    6

Answer

Correct Answer: 4

Explanation

Given data

  • Maximum magnetic quantum number ml = +3 ⇒ orbital angular momentum quantum number l = 3.

Concept/ApproachFor hydrogenic orbits, nl + 1. The number of standing waves around the orbit equals n (since 2πr = nλ).

Step-by-stepl = 3 ⇒ the smallest allowed principal quantum number is n = l + 1 = 4.Therefore, number of waves = n = 4.

Final Answer4

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