Vapour pressure correlation name check:\nThe empirical equation log10 P = A − B/(t + C) for pure components is known as the ________ equation.

Difficulty: Easy

Correct Answer: Antoine equation

Explanation:


Introduction / Context:
Correlations for pure-component vapor pressures are used in VLE design and simulation. A widely used empirical fit is the Antoine equation, convenient over moderate temperature ranges.



Given Data / Assumptions:

  • Equation form: log10 P = A − B/(t + C).
  • P is often in mmHg or bar depending on parameterization; t is temperature (commonly °C).


Concept / Approach:
Recognize the canonical form and its name. The Antoine equation is a three-parameter modification of the Clausius–Clapeyron relation that improves fitting accuracy across limited ranges.



Step-by-Step Reasoning:

Match form: log10 P vs 1/(t + C) with constants A, B, C → Antoine.Other listed items are unrelated: Kopp’s and Trouton’s are rules of thumb; Kistyakowsky is a different correlation family; Redlich–Kwong is an equation of state.


Verification / Alternative check:
Process simulators store Antoine constants for thousands of compounds, confirming the naming convention.



Why Other Options Are Wrong:

  • They do not correspond to the given functional form for vapor pressure.


Common Pitfalls:
Using Antoine constants outside their valid temperature range; mixing units for P without matching the fitted constants.



Final Answer:
Antoine equation

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