Kinetic theory link: For molecular speeds in a gas, the characteristic speed (e.g., root-mean-square speed) varies with absolute temperature T as __________.
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Adirectly proportional to T
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Bdirectly proportional to √T
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Cdirectly proportional to T^2
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Dinversely proportional to T
Answer
Correct Answer: directly proportional to √T
Explanation
Introduction / Context:The kinetic theory of gases relates molecular speed distributions to temperature and molecular mass. The root-mean-square (rms) speed, most probable speed, and average speed all scale with the square root of temperature for a given gas.
Given Data / Assumptions:
- Ideal-gas behavior; negligible intermolecular potential effects for the scaling argument.
- Fixed molar mass M for the gas under consideration.
Concept / Approach:The rms speed is u_rms = √(3 R T / M) for a gas of molar mass M. Both the average speed and the most probable speed have similar √T dependence with different constants (u_avg = √(8 R T / (π M)), u_mp = √(2 R T / M)). Therefore, any representative molecular speed scales as the square root of absolute temperature, not linearly with T.
Step-by-Step Solution:Recall u_rms = √(3 R T / M).Hold M and R constant for a given gas.Therefore, u_rms ∝ √T.
Verification / Alternative check:Plotting measured speed versus temperature on log–log axes gives a slope of 0.5, confirming the square-root dependence.
Why Other Options Are Wrong:Proportional to T or T^2: would vastly overpredict speed increases with temperature.Inversely proportional to T: contradicts the fundamental kinetic theory relation.
Common Pitfalls:Confusing pressure dependence with temperature scaling; assuming linearity out of habit; ignoring molecular mass in the complete expression.
Final Answer:directly proportional to √T