When rust forms on a metal object, which metal is reacting with oxygen and moisture to produce this reddish brown compound?

Difficulty: Easy

Correct Answer: Iron, forming reddish brown hydrated iron oxide called rust

Explanation:


Introduction / Context:
This chemistry question asks you to identify which metal produces rust when it reacts with oxygen and moisture. Understanding rusting is important for everyday life, engineering, and corrosion prevention. Many metals form oxides, but the term rust is used in a specific way in science and in common speech, and recognising this helps you answer the question correctly.


Given Data / Assumptions:


    • Rust is described as a reddish brown compound formed by reaction with oxygen and moisture.
    • The metals listed are aluminium, silver, copper, and iron.
    • Basic school level knowledge of corrosion and common metal oxides is assumed.


Concept / Approach:
Although many metals corrode and form oxides, the word rust is technically reserved for the corrosion products of iron and iron based alloys such as steel. Rust is primarily hydrated iron(III) oxide, often written as Fe2O3·xH2O, and appears as a reddish brown flaky coating on the surface of iron objects exposed to air and water. Aluminium forms a thin, protective aluminium oxide layer that is usually colourless or dull grey, not red and flaky. Silver tarnishes by forming black silver sulphide, not rust. Copper forms green patinas of basic copper carbonate and other compounds. Therefore, when the question mentions rust, it is specifically referring to the corrosion of iron.


Step-by-Step Solution:

Step 1: Recall that rust is commonly seen on old iron gates, bridges, and tools, giving them a reddish brown appearance. Step 2: Identify that these structures are typically made of iron or steel, which contain iron as the main metal. Step 3: Remember that rust forms when iron reacts with oxygen and water, producing hydrated iron(III) oxides. Step 4: Compare with other metals: aluminium forms a protective oxide that does not flake off easily, silver turns black due to silver sulphide, and copper turns green due to corrosion products like basic copper carbonate. Step 5: Conclude that among the options, iron is the metal that actually forms rust in the strict chemical sense.


Verification / Alternative check:
Standard chemistry textbooks define rusting as the corrosion of iron and illustrate it by showing iron nails or steel objects kept in damp air. They highlight that rust is hydrated iron(III) oxide and explain conditions that accelerate rusting, such as presence of salts. In contrast, sections on other metals refer to tarnishing of silver and patina formation on copper, using different terms and colours. This consistent usage confirms that rust is specifically linked to iron, supporting option D as the correct answer.


Why Other Options Are Wrong:

Aluminium, forming a thick red flaky oxide called rust, is wrong because aluminium oxide forms a thin, usually colourless or dull grey protective layer, not typical rust.

Silver, forming black silver sulphide called rust, is incorrect because this process is called tarnishing, not rusting.

Copper, forming greenish basic copper carbonate called rust, is wrong because the green layer on copper is known as patina, not rust.


Common Pitfalls:
Some learners casually use the word rust for any kind of corrosion or colour change in metals, which can lead to confusion in exam questions. Another pitfall is to associate rust with any reddish or greenish colour without considering the specific metal involved. To avoid these errors, remember the chemical definition: rust is the reddish brown hydrated iron oxide that forms when iron reacts with oxygen and moisture, so iron is the correct choice.

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