Universal (molar) gas constant – relation to specific gas constant The universal gas constant R_u (per mole) is related to a gas’s specific gas constant R (per unit mass) by which product?
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Amolecular mass * specific gas constant (R)
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Batomic mass * specific gas constant (R)
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Cmolecular mass * c_p (specific heat at constant pressure)
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Dmolecular mass * c_v (specific heat at constant volume)
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Emolar mass divided by c_p
Answer
Correct Answer: molecular mass * specific gas constant (R)
Explanation
Introduction / Context:Two common forms of the gas constant appear in thermodynamics: R_u, the universal (molar) gas constant with units J/(mol·K), and R, the specific gas constant with units J/(kg·K). Converting between them requires the molar (molecular) mass of the gas.
Given Data / Assumptions:
- R_u ≈ 8.314 kJ/(kmol·K) or 8.314 J/(mol·K).
- R depends on the particular gas: R = R_u / M.
- M is the molar (molecular) mass in kg/kmol or kg/mol consistent with units.
Concept / Approach:The relationship is R_u = M * R, where M is the molar mass of the gas and R is its specific gas constant on a per-mass basis. This follows directly from writing the ideal-gas equation either as p * V = n * R_u * T (molar form) or p * v = R * T (specific form) and substituting n = m/M.
Step-by-Step Solution:Start with p * V = n * R_u * T and n = m / M.Divide by mass m to get p * v = (R_u / M) * T.Identify R = R_u / M → rearrange to R_u = M * R.Therefore, the correct product is molecular mass times specific gas constant.
Verification / Alternative check:For air: M ≈ 28.97 kg/kmol, R ≈ 0.287 kJ/(kg·K). Product M * R ≈ 28.97 * 0.287 ≈ 8.314 kJ/(kmol·K) = R_u, confirming the relation.
Why Other Options Are Wrong:
- Atomic mass pertains to single atoms; many gases are diatomic or polyatomic; the correct parameter is molar mass of the gas species.
- Products with c_p or c_v do not produce R_u; instead, for ideal gases c_p − c_v = R (not R_u).
- “Molar mass divided by c_p” is dimensionally inconsistent.
Common Pitfalls:Mixing per-mole and per-mass quantities. Always ensure unit consistency when converting between R and R_u.
Final Answer:molecular mass * specific gas constant (R)