Difficulty: Easy
Correct Answer: Francium
Explanation:
Introduction / Context:
This periodic table question tests understanding of trends in atomic radius. Atomic radius is a measure of the size of an atom. In general, atomic radius increases as you move down a group and decreases as you move from left to right across a period. Using these trends, we can compare elements such as helium, neon, cesium, and francium to determine which has the largest atomic radius.
Given Data / Assumptions:
- The elements to compare are Neon (Ne), Francium (Fr), Helium (He), and Cesium (Cs).
- We consider neutral atoms in their ground states.
- We use general periodic trends in atomic size without worrying about small irregularities in measured values.
Concept / Approach:
Atomic radius generally increases as we go down a group because additional electron shells are added, making atoms larger. It generally decreases across a period from left to right because increasing nuclear charge pulls the electrons closer to the nucleus. Helium and neon are small noble gases in the first and second periods, respectively. Cesium and francium are alkali metals in groups at the left side of the table and in lower periods, with francium located below cesium. Therefore, among the given choices, francium is expected to have the largest atomic radius.
Step-by-Step Solution:
Step 1: Identify the group and period of each element. Helium is in period 1, group 18. Neon is in period 2, group 18. Cesium is in period 6, group 1. Francium is in period 7, group 1.
Step 2: Recall the trend down a group. As you go down group 1 from lithium to sodium, potassium, rubidium, cesium, and francium, the atoms become larger due to additional electron shells.
Step 3: Helium and neon are near the top of the periodic table, with very small atomic radii because they have few electron shells and high effective nuclear charge for their small size.
Step 4: Cesium is already a very large atom in period 6, but francium lies below it in period 7, so francium has one more electron shell than cesium, making it even larger.
Step 5: Comparing all four elements, francium, the bottom member of group 1, has the largest atomic radius among the choices.
Verification / Alternative check:
Periodic table charts that show atomic radius trends typically colour or size elements to indicate relative atomic size. These diagrams highlight that alkali metals at the bottom left, especially francium, have the largest radii. In contrast, noble gases at the top right have some of the smallest atomic radii. Looking at such charts confirms that francium is larger than cesium and significantly larger than helium or neon. Even if experimental data for francium are limited due to its radioactivity, general trends and theoretical calculations agree that francium has the largest radius among the listed elements.
Why Other Options Are Wrong:
- Neon: Neon is a noble gas in period 2 and has a relatively small atomic radius compared with heavier elements in lower periods.
Why Other Options Are Wrong (continued):
- Helium: Helium is in period 1 and has one of the smallest atomic radii in the periodic table, so it cannot be the largest among these options.
- Cesium: Cesium is very large, but francium lies below cesium in the same group and therefore has a larger radius than cesium.
Common Pitfalls:
Students sometimes mistakenly think that heavier elements always have smaller radii due to stronger nuclear attraction, forgetting the dominant effect of additional shells. Another source of confusion is mixing up atomic radius with ionic radius, which follows slightly different patterns. To avoid errors, remember the simple rule that atomic size increases down a group and decreases across a period, which places the largest atoms at the bottom left of the periodic table, near francium.
Final Answer:
Francium has the largest atomic radius among the given elements.
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