Gas constant R – relation to specific heats For a calorically perfect ideal gas, the gas constant R is equal to which of the following combinations of the mass-specific heat capacities?
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Asum of two specific heats
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Bdifference of two specific heats
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Cproduct of two specific heats
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Dratio of two specific heats
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Esquare of the specific heat at constant pressure
Answer
Correct Answer: difference of two specific heats
Explanation
Introduction / Context:The link between the gas constant R and the specific heats cp and cv is central to ideal-gas thermodynamics. Remembering the correct algebraic relation prevents frequent mistakes in property calculations and cycle analysis.
Given Data / Assumptions:
- Ideal gas with constant specific heats (calorically perfect).
- Mass-specific heats cp and cv.
- Definition of gamma: γ = cp / cv.
Concept / Approach:
For ideal gases, enthalpy h = cp * T and internal energy u = cv * T. The enthalpy–internal energy relation is h − u = R * T, which rearranges to (cp − cv) * T = R * T. Cancel T to obtain the fundamental identity R = cp − cv. This holds on both a per–unit-mass and per–mole basis (with appropriate R values).
Step-by-Step Solution:
Start from h = u + p * v and p * v = R * T (ideal gas).Differentiate with respect to T: dh/dT − du/dT = R.Recognize dh/dT = cp and du/dT = cv ⇒ R = cp − cv.Verification / Alternative check:
Measured values for air at room temperature: cp ≈ 1.005 kJ/kg·K, cv ≈ 0.718 kJ/kg·K, difference ≈ 0.287 kJ/kg·K, matching R for air.
Why Other Options Are Wrong:
Sum/product/ratio/square do not satisfy the identity derived from h − u and the ideal-gas equation of state.
Common Pitfalls:
Confusing γ = cp / cv with R = cp − cv; both appear often but represent distinct relations.
Final Answer:
difference of two specific heats